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id="2uq6uxdxmoz" class="news_detail"> <h1 class="detail_title">鈉型陽離子交換樹脂的工業(yè)應(yīng)用與影響因素</h1> <div id="2uq6uxdxmoz" class="details_tongji">更新時(shí)間：2023-06-14　點(diǎn)擊量：<span id="Click">300</span> </div> <div id="2uq6uxdxmoz" class="n_con"> <p>鈉型陽離子交換樹脂的工業(yè)應(yīng)用與影響因素</p><p><br/></p><p style="text-align: left"><span style="font-size:16px"> </span></p><p style="text-align: left"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">產(chǎn)品名稱:001×7強(qiáng)酸性苯乙烯系陽離子交換樹脂</span></span></span></p><p style="text-align: left"><span style="font-size:16px"> </span></p><p style="text-align: left"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">詳細(xì)信息:</span></span></span></p><p style="text-align: left"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">二、國外應(yīng)牌號<br/>美國：Amberlite IR-120; Dowex 50-X8; 德國：Lewatit S-100;日本：Diaion SK-1B<br/>三、執(zhí)行標(biāo)準(zhǔn)<br/>GB13659-92 DL519-93 SH2605.01-1997 Q/JH105-2002<br/>四、理化性能</span></span></span></p><div id="2uq6uxdxmoz" class="tabledivclass" style="width: 99%; float: left;"><table border="1" cellpadding="0" cellspacing="0" style="border-collapse: collapse; max-width: 748px;" align="left"><tbody><tr class="firstRow"><td colspan="2" style="width: 86px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">名稱</span></span></span></p></td><td colspan="2" style="width: 170px"><p style="text-align: left"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">001×7H/Na </span></span></span></p></td><td colspan="2" style="width: 161px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">001×7FC H/Na</span></span></span></p></td><td colspan="2" style="width: 161px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">001×7MB H/Na</span></span></span></p></td><td><p><span style="font-size:16px"> </span></p></td></tr><tr><td colspan="2" style="width: 86px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">全交換容量 mmol/g≥</span></span></span></p></td><td colspan="4" style="width: 331px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">5.00/4.50</span></span></span></p></td><td colspan="2" style="width: 161px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">4.90/4.40</span></span></span></p></td><td><p><span style="font-size:16px"> </span></p></td></tr><tr><td><p><span style="font-size:16px"> </span></p></td><td colspan="2" style="width: 86px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">體積交換容量mmol/ml≥</span></span></span></p></td><td colspan="4" style="width: 331px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">1.75/1.90</span></span></span></p></td><td colspan="2" style="width: 161px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">1.70/1.80</span></span></span></p></td></tr><tr><td colspan="2" style="width: 86px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">含水量</span></span></span></p></td><td colspan="6" style="width: 492px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">51-56/45-50</span></span></span></p></td><td><p><span style="font-size:16px"> </span></p></td></tr><tr><td><p><span style="font-size:16px"> </span></p></td><td colspan="2" style="width: 86px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">濕視密度g/ml</span></span></span></p></td><td colspan="6" style="width: 492px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">0.73-0.83/0.77-0.87</span></span></span></p></td></tr><tr><td colspan="2" rowspan="2" style="width: 86px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">粒度</span></span></span></p></td><td colspan="2" style="width: 170px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">(0.315-1.25mm)≥95</span></span></span></p></td><td colspan="2" style="width: 161px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">(0.45-1.25mm)≥95</span></span></span></p></td><td colspan="2" style="width: 161px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">(0.71-1.25mm)≥95</span></span></span></p></td><td><p><span style="font-size:16px"> </span></p></td></tr><tr><td colspan="2" style="width: 170px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">(<0.315mm)≤1</span></span></span></p></td><td colspan="2" style="width: 161px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">(<0.45mm)≤1</span></span></span></p></td><td colspan="2" style="width: 161px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">(>0.71mm)≤1</span></span></span></p></td><td><p><span style="font-size:16px"> </span></p></td></tr><tr><td colspan="2" style="width: 86px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">有效粒徑mm</span></span></span></p></td><td colspan="2" style="width: 170px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">0.40-0.60</span></span></span></p></td><td colspan="2" style="width: 161px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">≥0.05</span></span></span></p></td><td colspan="2" style="width: 161px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">0.75-0.95</span></span></span></p></td><td><p><span style="font-size:16px"> </span></p></td></tr><tr><td colspan="2" style="width: 86px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">均一系數(shù)≤</span></span></span></p></td><td colspan="4" style="width: 331px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">1.60</span></span></span></p></td><td colspan="2" style="width: 161px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">1.40</span></span></span></p></td><td><p><span style="font-size:16px"> </span></p></td></tr><tr><td colspan="2" style="width: 86px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">磨后圓球率 ≥</span></span></span></p></td><td colspan="6" style="width: 492px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">90</span></span></span></p></td><td><p><span style="font-size:16px"> </span></p></td></tr><tr><td colspan="2" style="width: 86px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">外形 </span></span></span></p></td><td colspan="2" style="width: 170px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">金黃至棕褐色球狀顆粒</span></span></span></p></td><td colspan="2" style="width: 161px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">金黃至棕褐色球狀顆粒</span></span></span></p></td><td colspan="2" style="width: 161px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">金黃至棕褐色球狀顆粒</span></span></span></p></td><td><p><span style="font-size:16px"> </span></p></td></tr><tr><td><p><span style="font-size:16px"> </span></p></td><td colspan="2" style="width: 86px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">出廠型式</span></span></span></p></td><td colspan="2" style="width: 170px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">Na</span></span></span></p></td><td colspan="2" style="width: 161px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">Na</span></span></span></p></td><td colspan="2" style="width: 161px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">Na</span></span></span></p></td></tr><tr><td><p><span style="font-size:16px"> </span></p></td><td colspan="2" style="width: 86px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">用途</span></span></span></p></td><td colspan="2" style="width: 170px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">通用</span></span></span></p></td><td colspan="2" style="width: 161px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">浮動(dòng)床</span></span></span></p></td><td colspan="2" style="width: 161px"><p style="text-align: center"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">混床</span></span></span></p></td></tr><tr><td> </td><td> </td><td> </td><td> </td><td> </td><td> </td><td> </td><td> </td><td> </td></tr></tbody></table></div><p style="text-align: left"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">出廠型式：Na型外觀：金黃至棕褐色球狀顆粒。<br/>五、指標(biāo)：<br/>1．PH范圍：1-14<br/>2．使用溫度：氫型≤100℃，鈉型≤120℃，<br/>3．轉(zhuǎn)型膨脹率：（Na+→H+）8-10<br/>4．樹脂層高度：1.5m以上。<br/>5．再生液濃度 NaCl:8-10,<br/>　　　　　　　HCl:4-5.<br/>6．再生液用量：<br/>　　NaCl（8-10）體積：樹脂體積=1.5-2:1.<br/>　　HCl(4-5)體積：樹脂體積=2-3:1.<br/>7．再生液流速： 5-8 m/h.<br/>8．再生接觸時(shí)間： 45-60 min.<br/>9．正洗流速： 10-20 m/h<br/>10．正洗時(shí)間：約30 min<br/>11．運(yùn)行流速： 15-30 m/h<br/>12．交換容量：≥1000mol/m3<br/>六、主要用途<br/>用于水的處理（包括硬水軟化、高壓爐水、無離子水、注射水、海水淡化等），廢水中貴金屬的回收，抗生素的提純，代替人體內(nèi)腎臟的作用。<br/>七、包裝，貯運(yùn)<br/>本產(chǎn)品用內(nèi)襯塑料袋的編織袋包裝，每袋25kg，也可根據(jù)需求用塑料桶或其它容器包裝，本產(chǎn)品為非危險(xiǎn)品。貯運(yùn)溫度5-40℃，嚴(yán)禁脫水、曝曬。</span></span></span></p><p style="text-align: left"><span style="font-size:16px"> </span></p><p style="text-align: left"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">陰、陽離子交換樹脂樹脂的貯存：</span></span></span></p><p style="text-align: left"><span style="font-size:16px"> <span style="color:black"><span style="font-family:宋體">離子交換樹脂肪內(nèi)含有一定量的水份，在運(yùn)輸及貯存過程中應(yīng)盡量保持這部分水。如貯存過程中樹脂脫了水，應(yīng)先用濃食鹽水（-10）浸泡，再逐漸稀釋，不得直接放于水中，以免樹脂急劇膨脹而破碎。在長期貯存中，強(qiáng)型樹脂應(yīng)轉(zhuǎn)變成鹽型，弱型樹脂可轉(zhuǎn)變成相應(yīng)的氫型或游離堿型也可轉(zhuǎn)為鹽型，然后浸泡在潔凈的水中。樹脂在貯存或運(yùn)輸過程中，應(yīng)保持在5-40癈的溫度環(huán)境中，避免過冷或過熱，影響質(zhì)量。若冬季沒有保溫設(shè)備時(shí)，可將樹脂貯存在食鹽水中，食鹽水的溫度可根據(jù)氣溫而定。</span></span><br/><span style="color:black"><span style="font-family:宋體">新樹脂的預(yù)處理：</span></span></span></p><p style="text-align: left"><span style="font-size:16px"> <span style="color:black"><span style="font-family:宋體">新樹脂常含有溶劑、未參加聚合反應(yīng)的物質(zhì)和少量低聚合物，還可能吸著鐵、鋁、銅等重金屬離子。當(dāng)樹脂與水、酸、堿或其他溶液相接觸時(shí)，上述可溶性雜質(zhì)就會(huì)轉(zhuǎn)入溶液中，在使用初期污染出水水質(zhì)。所以，新樹脂在投運(yùn)前要進(jìn)行預(yù)處理。</span></span></span></p><p style="text-align: left"><span style="font-size:16px"> </span></p><p style="text-align: left"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">陽樹脂的預(yù)處理</span></span></span></p><p style="text-align: left"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">陽樹脂預(yù)處理步驟如下：</span></span></span></p><p style="text-align: left"><span style="font-size:16px"> <span style="color:black"><span style="font-family:宋體">首先使用飽和食鹽水，取其量約等于被處理樹脂體積的兩倍，將樹脂置于食鹽溶液中浸泡18-20小時(shí)，然后放盡食鹽水，用清水漂洗凈，使排出水不帶黃色;其次再用2-4NaOH溶液，其量與上相同，在其中浸泡2-4小時(shí)（或作小流量清洗），放盡堿液后，沖洗樹脂直至排出水接近中性為止。后用5HCL溶液，其量亦與上述相同，浸泡4-8小時(shí)，放盡酸液，用清</span></span></span></p><p style="text-align: left"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">水漂流至中性待用。</span></span></span></p><p style="text-align: left"><span style="font-size:16px"> <span style="color:black"><span style="font-family:宋體">陰樹脂的預(yù)處理</span></span></span></p><p style="text-align: left"><span style="font-size:16px"> <span style="color:black"><span style="font-family:宋體">其預(yù)處理方法中的步與陽樹脂預(yù)處理方法中的步相同；而后用</span></span></span></p><p style="text-align: left"><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">5HCL浸泡4-8小時(shí)，然后放盡酸液，用水清洗至中性；而后用2-4NaOH溶</span></span></span></p><p><span style="font-size:16px"><span style="color:black"><span style="font-family:宋體">液浸泡4-8小時(shí)后，放盡堿液，用清水洗至中性待用。</span></span></span></p><p>鈉型陽離子交換樹脂的工業(yè)應(yīng)用與影響因素</p><p><span><strong><span>　　</span>離子交換樹脂的工業(yè)應(yīng)用</strong></span></p><p>　　1、用于水處理的量很大，占離子交換樹脂的產(chǎn)量的90以上。</p><p>　　離子交換樹脂的工業(yè)用水里存在鈣、鎂、兩價(jià)和三價(jià)的鐵離子，易使管道和鍋爐結(jié)垢。除去這些金屬離子的過程，稱為水的軟化。早期水的軟化是使用沸石及磺化煤，現(xiàn)多用聚苯乙烯磺酸型離子交換樹脂。用于原子能、半導(dǎo)體、電子工業(yè)、高溫高壓鍋爐的水，要求高質(zhì)量的無離子水。采用樹脂混合床法可使水去離子化，即將氫型強(qiáng)酸樹脂與羥型強(qiáng)堿樹脂混合均勻后放入一交換柱內(nèi)，通過交換柱出來的水，僅含0.006ppm的離子性溶質(zhì)(水的電阻率為1.8×107歐·厘米)，此純度相當(dāng)于用石英容器重蒸餾28次所獲得的水。</p><p>　　2、從貧鈾礦里將鈾分離、濃縮、提純和回收，分離和提純稀土元素和貴金屬，回收電鍍?nèi)芤褐械你t及人造絲廢液中的銅等。</p><p>　　3、用于醫(yī)學(xué)和醫(yī)藥上的回收、分離和提純，如抗生素、氨基酸及生物堿的分離提純，用量相當(dāng)大。</p><p>　　4、在有機(jī)合成中常用酸和堿作催化劑進(jìn)行酯化、水解、酯交換、醇醛縮合、水合等反應(yīng)。用離子交換樹脂代替無機(jī)酸、堿、同樣可進(jìn)行上述反應(yīng)，且優(yōu)點(diǎn)更多。如樹脂可反復(fù)使用，產(chǎn)品容易分離，反應(yīng)器不會(huì)被腐蝕，不污染環(huán)境，反應(yīng)容易控制等。</p><p></p><p>離子交換樹脂</p><p>　　5、用于分析化學(xué)，例如水中離子濃度的分析、稀土分析、生化分離，以及月球上痕量物質(zhì)的分析等。</p><p>　　6、用于糖、生物制品、甘油、酒等的脫色。</p><p>　　7、去除電鍍廢液里的金屬離子，回收電影制片廢液里的有用物質(zhì)，如苯酚及其衍生物等。</p><p>　　8、用于外消旋物的拆分、固相合成，以及作為化學(xué)試劑等。</p><p></p><p>離子交換樹脂</p><p><span><strong><span>　　</span>離子交換樹脂影響離子交換反應(yīng)的因素</strong></span></p><p>　　離子交換反應(yīng)主要發(fā)生在樹脂內(nèi)部。在離子交換反應(yīng)前，溶液里的反應(yīng)物必須能擴(kuò)散進(jìn)樹脂內(nèi)部。擴(kuò)散速率與樹脂體上毛細(xì)孔大小有關(guān)，而毛細(xì)孔的大小，與合成時(shí)加入的交聯(lián)劑的量有關(guān)。交聯(lián)劑用量少的，樹脂的交聯(lián)度小,毛細(xì)孔孔徑就大，反應(yīng)物就容易擴(kuò)散進(jìn)去；交聯(lián)劑用量多的，樹脂的交聯(lián)度大，毛細(xì)孔孔徑就小，反應(yīng)物就不容易進(jìn)去。因此，往往利用交聯(lián)度不同的樹脂，將分子量不同的化合物分開。</p><p></p><p>離子交換樹脂</p><p>　　另外，溶液里的離子濃度與樹脂的交換量也是影響反應(yīng)物擴(kuò)散進(jìn)樹脂內(nèi)部的因素之一。若溶液里的離子濃度比較高，而樹脂的交換量又比較小時(shí)，則離子很易擴(kuò)散進(jìn)樹脂內(nèi)部進(jìn)行交換；反之，若溶液里的離子濃度較小，樹脂的交換量又高，溶液里的離子不易擴(kuò)散進(jìn)去，故交換反應(yīng)不能進(jìn)行，因而去除溶液里少量離子是困難的。</p> 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